95th Canadian Chemistry Conference and Exhibition


Inorganic Chemistry

Sunday AM

IN2Macleod E3

Metal Mediated Polymerization (joint with MS)

Organizer(s) - M. Shaver, P. Hayes
Chair(s) - P. Hayes

08:20 00052 New Alkaline Earth and Rare Earth Initiators for the Ring-opening Polymerization of rac-Lactide Clark L., Cushion M.G., Dyer H.E., Unruangsri J., *$Mountford P.
09:00 00053 Ring-opening Polymerization of Cyclic Esters using Zinc and Lithium Amine-phenolate Complexes *$Kerton F.M., Ikpo N., Hoffmann C.
09:20 00054 Complex Geometry and Catalyst Performance in Lactide Polymerization with Diketiminate Complexes Whitehorne T.J., Druoin F., Vabre B., *Schaper F.
09:40 00055 Cationic Zinc Lactide Polymerization Catalysts Supported by Chiral Bisphosphinimine Pincer Ligands *Sun H., $Hayes P.G.
10:00 Coffee Break
10:20 00056 Discrete Complexes of Divalent Main Group Metals: Stabilization with Secondary Interactions and Mechanisms in the Ring-Opening Polymerization of Cyclic Esters *Sarazin Y., Liu B., Poirier V., Carpentier J.F.
11:00 00057 Synthesis of 3-coordinate Diamido Aluminum Complexes for Applications in the Ring Opening Polymerizations of Cyclic Esters *$Foley S.R., Wu S.-C., Schatte G.
11:20 00058 Isoselective Polymerization of Lactide with Chiral Indium Complexes *$Mehrkhodavandi P., Aluthge D.C., Yu I., Osten K.M., Xu C.
11:40 00059 Postmetallocene Catalysts for the Stereoselective Polymerization of Petroleum and Biomass Derived Monomers Okuda J.
12:20 End of Session

IN3Macleod E2

Symposium on the Applications of Physical Methods to Coordination Chemistry in Honour of Barry Lever

Organizer(s) - R.J. Crutchley
Chair(s) - R.J. Crutchley, P.C. Ford

08:00 00060 Nanomaterial Antennae in Photo-delivery of Bioactive Molecules *$Ford P.C., Garcia J., Burks P., Pierri A., Crisalli M.
08:40 00061 Raman Spectromicroscopy and X-ray Powder Diffraction Studies of Selected Inorganic Materials Under Extreme Conditions *$Butler I.S.
09:00 00062 Silicon Nanocrystals: Why Do Some Colloidal Si-NCs Exhibit Size Dependent Photoluminescence While Others Simply Have the Blues? *$Veinot J.G.C., Dasog M., Regli S., Yang Z.
09:20 00063 catena-Phosphorus Cations *$Burford N., Carpenter Y-Y, Conrad E.
09:40 00064 Electronic Spectroscopy of Gold(I) Compounds. Luminescence Properties and Intermolecular Interactions *Reber C.
10:00 Coffee Break
10:20 00065 Electrochemistry of Multilayer Films Based on Mixed-valent Dinuclear Ru Complexes Bearing Tetrapod Phosphonate Groups *$Haga M., Nakabayashi T.
11:00 00066 Binuclear Ruthenium Complexes Bridged by Verdazyl Radicals: A New Spin on Mixed Valence McKinnon S.D.J., *Hicks R.G., Lever A.B.P.
11:20 00067 New Redox-Active Metallo-Phthalocyanines and Related Isoindoline-based Complexes: Preparation, Structure and Properties *Leznoff D.B.
11:40 00068 Spectroscopic Effects of Potential Surface Coupling: Interference Dips and Excited Sate Mixed Valence Zink J.I.
12:00 End of Session

IN4Macleod E1

Ligand Design (joint with OR)

Organizer(s) - S. Johnson, T. Storr
Chair(s) - S. Johnson, T. Hayton

08:00 00069 Development of a New Class of Anionic N-Heterocyclic Carbene Ligands: Structural Analysis and Catalytic Activity Guernon H., *$Legault C.Y.
08:20 00070 A Thorough Investigation of N-H Bond Activation Mediated by Rhodium and Iridium Bis(phosphino)silyl Pincer Complexes Morgan E., $Turculet L.
08:40 00071 Ligand Effects in the Metal-Mediated Radical Reactivity of CpCr(LX) Complexes *Smith K.M.
09:00 00072 Ligand Designs Based on Amido and Phosphine Donor Combinations Wambach T.C., Halcovitch N.R., Wence L., *$Fryzuk M.D.
09:20 00073 Ligand Design for Base Metal Catalysis and Asymmetric Variants *$Chirik P.J., Monfette S., Hoyt J.M., Darmon J.M., Friedfeld M.
10:00 Coffee Break
10:20 00074 Synthesis and Characterization of New Alkali Metal and Transition Metal Corrole Complexes Buckley H.L., Gryko D.T., $Arnold J.
10:40 00075 Utilizing Metal-Ligand Bifunctional Reactivity for the Activation of Small Molecules Employing a Tripodal Aminophosphine Ruthenium Complex Sgro M.J., $Stephan D.W.
11:00 00076 Ambiphilic Molecules: Exploring a Novel Paradigm in Coordination Chemistry *$Fontaine F.-G., Boudreau J., Courtemanche M.-A., Desroches M.
11:20 00077 NHC Based PCP Pincer Ligands and their Transition Metal Complexes *Borau-Garcia J., $Roesler R., Tuononen H.M.
11:40 00078 The Evolution of a Copper Precursor: Ligand Design and Thermolysis *$Barry S.T., Coyle J.P.
12:00 End of Session

IN8Glen 201

General

Organizer(s) - R. Roesler
Chair(s) - E. Rivard

08:00 00079 Aminoboranes, Phosphinoboranes and Alkenes: Isoelectronic Species with Contrasting Reactivity Towards H2 Robertson A.P.M., Whittell G.R., Staubitz A., Lee K., *Manners I.
08:20 00080 Controlled Photo Release of B(C6F5)3: A Photo Lewis Acid Generator Khalimon A.Y., Marwitz A.J.V., *Piers W.E.
08:40 00081 Insights into the Mechanism of Metal-Free Hydrogen Transfer Between Amine-Boranes and Aminoboranes *Leitao E.M., Robertson A.P.M., Stubbs N.E., Helten H., Lloyd-Jones G.C., $Manners I.
09:00 00082 Reactivity of Saturated Ruthenium Acetylide Complexes with Electrophilic Boranes Boone M.P., $Stephan D.W.
09:20 00083 Light-Enabled Unusual C-H Activation of N, C-Chelate Organoboron Compounds Rao Y., Amarne H., Chen L., *$Wang S.
09:40 00084 Reactivity of Vinylborane Ligands with Low-Valent Late Transition Metals Mehta M., Kolpin K.B., *$Emslie D.J.H.
10:00 Coffee Break
10:20 00085 Di- and Triblock Copolymers Involving P=C Multiple Bonds $Conrad E.D., *Gates D.P.
10:40 00086 Synthesis and Characterization of Chalcogenophosphonium Cations Lucas S.H., *$Burford N.
11:00 00087 Studies on 1,2,4-Dithiazolyls, a New Class of Sulphur-Nitrogen Radicals Hayward J.J., *Rawson J.M.
11:20 00088 Synthesis and characterization of N-(triethoxysilylmethyl)phthalimide, N-((2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3.0]undecan-1-yloxy)methyl)phthalimide, N-((sila-2,10,11-trioxa-6-aza-3,4;8,9;12,13-tris(4,6-dimethylbenzo)[4.4.4.0]tricyclotetradecane)methyl))phthalimide. Mangat S., *$Singh G.
11:40 00089 Advanced Energetic Matererials: Compounds and Strategies Klapötke T.M., Piercey D.G., Stierstorfer J.
12:00 00090 Analysis of Bonding and Electronic Properties of Heavier Congeners of Alkene and Alkyne Based on NOCV-ETS and SF-CV-DFT Calculations Seidu I., *Ziegler T.
12:20 End of Session

INGlen 205

Diversity and Challenges of Inorganic Molecular and Materials Modelling (joint with PT7)

08:00 See PT7.

12:20 End of Session

INMacleod D

Molecular Design of Optical, Photonic and Electronic Materials (joint with MT2)

08:00 See MT2.

12:20 End of Session

INMacleod C

Symposium on Homogeneous and Heterogeneous Catalysis in Honour of Howard Alper (joint with OR2)

08:00 See OR2.

12:20 End of Session


Sunday PM

IN2Macleod E3

Metal Mediated Polymerization (joint with MS)

Organizer(s) - M. Shaver, P. Hayes
Chair(s) - F. Kerton

13:40 00260 Metal Catalyzed Copolymerization of Olefins with Polar Vinyl Monomers *$Jordan R.F.
14:20 00261 Towards Selective Ethylene Tetramerization Gambarotta S.
14:40 00262 First and Second Olefin Insertion in Cp2TiMe+: Regio- and Stereo-Selectivity Dunlop-Bričre A.F., Baird M.C., *$Budzelaar P.H.M.
15:00 00263 Toward a Step-By-Step Mechanistic Elucidation of Chain-End Stereocontrol in d0 Metallocene Catalyzed Polymerization of a-Substituted Olefins Dunlop-Bričre A.F., Budzelaar P.H.M., *Baird M.C.
15:20 00264 Structure Activity Relationships for Pd-Based Polymerization Catalysts *$Claverie J., Piche L., Daigle J.C.
15:40 End of Session

IN3Macleod E2

Symposium on the Applications of Physical Methods to Coordination Chemistry in Honour of Barry Lever

Organizer(s) - R.J. Crutchley
Chair(s) - L.K. Thompson, R.J. Crutchley

13:40 00265 Further Aspects of Non-Innocent Ligand Chemistry Lever A.B.P.
14:20 00266 Non-innocent Behaviour in Dinuclear Ruthenium Dicyanamidobenzene Complexes *$Crutchley R.J., Naklicki M.L., Choudhuri M., Kaim W., Sarkar B., Gorelsky S.
14:40 00267 Preparation and Study of Mono- and Dinuclear Ru(II) Complexes Bearing Non-innocent Ligands Kalinina D., Potvin P.G., *$Lever A.B.P.
15:00 00268 Mixed-valent Diruthenium Complexes with Metal Oxidation States beyond the II/III Combination Kaim W.
15:40 Coffee Break
16:00 00269 Directed Assembly of Polymetallic Lanthanide [nxn] Grid and Chain Complexes; SMM Behaviour with Square [2x2] Dy4 Grids Anwar M.U., Dawe L.N., Thompson L.K.
16:40 00270 The Fluoroborylene (BF) Ligand in Transition Metal Chemistry: A Comparison with the Isoelectronic Ubiquitous Carbonyl (CO) Ligand *$King R.B., Xu L., Li Q.-s., Xie Y., Schaefer H.F.
17:20 End of Session

IN4Macleod E1

Ligand Design (joint with OR)

Organizer(s) - S. Johnson, T. Storr
Chair(s) - K. Smith, U. Fekl

Strem Chemicals Award for Pure or Applied Inorganic Chemistry lecture:

13:40 00271 New Strategies in P,N Ligand Design: Applications in Challenging Late Metal-Catalyzed Transformations *$Stradiotto M.
14:20 00272 Structure and Reactivity of Bis(phosphinimine) Ancillary Ligands for Supporting Organolanthanide Complexes Johnson K.R.D., $Hayes P.G.
14:40 00273 Non-innocent Ligands in Small Molecule Activations *$Song D.
15:00 00274 Novel Metal-Organic Frameworks using Structure Directing, Shape-Persistent Ligands Crane A.K., Wong E.Y.L., Larson D.R., $MacLachlan M.J.
15:20 00275 Sensitivity of the Ethylene Oligomerization Catalytic Cycle to Ligand Features *$Gambarotta S.
15:40 Coffee Break
16:00 00276 New Ketimide Ligands for the Stabilization of High Oxidation States *$Hayton T.W.
16:40 00277 Ultra-Rigid Pincer Ligands in Actinide Organometallic and Redox Chemistry *$Emslie D.J.H., Andreychuk N.R., Vidjayacoumar B., Ilango S., Kolpin K.B., Cruz C.A., Ray M., Chu T.
17:00 00278 An Exploration in Ligand Modularity: The Search for Metalation Resistant Pincer Ligands to Support Organometallic f-Element Complexes Kamenz B.L., *Johnson K.R.D., $Hayes P.G.
17:20 End of Session

IN8Glen 201

General

Organizer(s) - R. Roesler
Chair(s) - S. Wang

13:40 00279 Fabricating Conducting Inorganic Polymers with Organometallic Chemistry *$Rivard E., Kang L., He G., Torres-Delgado W., Brandt J., Ramsay W., Shynkaruk O.
14:00 00280 Artificial Multi-Step Light Harvesting System *Ishitani O.
14:20 00281 Redox Active Transition Metal Complexes for Molecular Electronics *$Vos J.G.
14:40 00282 Spin Catalytic Isomerisation of Azo Bonds by Nitric Oxide Rosadiuk K., $Bohle D.S.
15:00 00283 Catalytic Strategies Using Ionic Liquids *Singer R.D., Sonar S., Cuthbert T., Durand A., Ambrose K.
15:20 00284 N-Alkyl-iminodiacetate Coordination Complexes and Metallomicelle Chemistry Applications Cull J.E.W., *$Scott J.
15:40 Coffee Break
16:00 00285 Comparative Study on Cd(II) Complex Formation with Thiourea and Selenourea in Solution using 113Cd NMR and X-ray Absorption Spectroscopy *$Jalilehvand F., Amini Z., Parmar K.
16:20 00286 Density Functional Theory Studies on the Electronic Structure of the Peroxide Intermediate and Peroxide Adduct in Multicopper Oxidases Zhekova H.R., *Ziegler T., Seth M.
16:40 00287 Spectroscopic and Theoretical Analysis of Non-innocent Schiff-base Systems Dunn T.J., $Storr T.
17:00 00288 The Metal-Solvent Interaction: A Time Resolved IR Study *Bengali A.A., $Darensbourg D.J.
17:20 End of Session

IN-PoExhibition Hall CD

Poster Session

From 18:00 until 19:30

18:00 00289 Design, Synthesis and Structural Study on Novel Isomorphous Complexes Based on "Pyridine-3-yl-pyridine-2-yl methylene amine" Mahmoudi A., Dehghanpour S., Najafi L.
18:00 00290 The Synthesis, Characterization and Crystal Structure of a New Copper(II) Complexes with Diimine Ligands *Khalaj M.
18:00 00291 Synthesis, Characterization and Structures of Zinc(II) Complexes with Bidentate Iminopyridine *$Khalaj M.
18:00 00292 Alkyl Modified DOTAM-Derived Ligands and Their Complexes with Selected Heavy Lanthanide(III) Cations: Synthesis and Magnetic Properties Suchy M., Elmehriki A.A.H., Milne M., Bartha R., $Hudson R.H.E.
18:00 00293 Ruthenium Complexes with the Electropolymerizable Pyrrole-containing 2,2'-Dipyridylamine Wong K.Y., Cheung K.C., Guo P., Lee L.Y.C., So M.H., Zhou Z.Y.
18:00 00294 Ferroelectric and Structural Study of the Lead-free Piezoelectric Material (1-x)AgNbO3-xK0.5Na0.5NbO3 *Zhang N., $Ye Z.-G.
18:00 00295 Novel Group 6 Complexes Relevant to Ketone Hydrogenation Catalysis van der Eide E.F., *Bullock R.M.
18:00 00296 Triarylboron-Appended Acetylacetonate Chelate Complexes: Structure and Emissive Properties Blight B.A., *$Wang S.
18:00 00297 Applications of Ligand Exchange Reactions Around Palladium(ii) in One-pot Synthesis of Coordination Assemblies Bandi S., Debata N.B., *$Chand D.K.
18:00 00298 Investigating New Reactivity of Monomeric Platinum(II) Hydroxides Stabilized by Bulky a-Diimine Ligands Lohr T.L., *$Piers W.E., Parvez M.
18:00 00299 Generation of Alkyl, Alkynyl and Alkoxy Phosphinidene Complexes from a Dichlorophosphido Precursor *Rajagopalan A.R., $Sterenberg B.T.
18:00 00300 Chiral Nematic Mesoporous Materials Terpstra A.S., *Shopsowitz K.E., $MacLachlan M.J.
18:00 00301 Formation of Phosphorus Heterocycles from Cationic Electrophilic Phosphinidene Complexes and Unusual Group Transfers from Non-Innocent Counterions Vaheesar K., Kuntz C.M., *$Sterenberg B.T.
18:00 00302 Ruthenium and Rhodium Complexes of Thioether-Alkynylborates Dahcheh F., *$Stephan D.W.
18:00 00303 Heterobimetallic Lanthanide-Gold Coordination Polymers: Structure and Emissive Properties of Isomorphous [nBu4N]2[Ln(NO3)4Au(CN)2] 1-D Chains Roberts R.J., Li X., Lacey T.F., Pan Z., *Patterson H.H., $Leznoff D.B.
18:00 00304 Palladium-catalyzed Amination Reactions of Aryl Halides Using a Newly Developed Catalyst Precursor Borjian Borojeni S., *Baird M.
18:00 00305 A Dynamic Metal-Organic Rotaxane Framework *Vukotic V.N., Harris K.J., Zhu K., Schurko R.W., $Loeb S.J.
18:00 00307 The Design and Synthesis of a Porous, Hydrophobic Phosphonate Ester Based MOF Kim S.R., *Taylor J.M., $Shimizu G.K.H.
18:00 00308 Cu Pincer Oxazolines, New Catalyst in Henry Reaction Taghvaee M., *Gossage R.A.
18:00 00309 Synthesis and Characterization of Rhenium(I) Tricarbonyl Diimine Complexes with a Photochromic Organoboron Moiety Wang N., Lu J.S., *$Wang S.
18:00 00310 CO2 Adsorbing Metal Organics Frameworks From 1,3,4,7-tetrakis(4-phosphonatophenyl)adamantane Bladek K.J., Taylor J.M., Shimizu G.K.H.
18:00 00311 Ion Recognition Through Bisbenzimidazole Based Rotaxanes *Baggi G., $Loeb S.J., Zhu K., Vukotic N.V.
18:00 00312 Phosphorus-Based Flame Retardants for Paper Priegert A.M., Siu P.W., Tian H.J., Hu T.Q., *$Gates D.P.
18:00 00313 Toward Fast Initiating and Propagating Ruthenium Catalysts Bates J.M., Monfette S., *$Fogg D.E.
18:00 00314 Preparation and Characterization of Copper(II) Hydroxide Dimer-based Coordination Polymers using d8 [Pt(SCN)4]2- and [Au(CN)4]- Building Blocks Savard D., Katz M.J., Cheng L.K.L., *Leznoff D.B.
18:00 00315 Investigation of Structural and Magnetic Properties of First and Second Row Transition Metals with N,N',N and S,N,S Pincer-type Ligands Ouanounou S., *Richeson D.S.
18:00 00316 The Design and Synthesis of Dicyanoaurate-based Birefringent Materials Thompson J.R., *Williams V.E., $Leznoff D.B.
18:00 00317 Ring-Chain Equilibria and Stereoselectivity in RCM Macrocyclizations Higman C.S., Monfette S., Robinson M., Payne P.R., *$Fogg D.E.
18:00 00318 CO2 Capture by Three Isomorphous Metal Organic Frameworks Martens I., *$Shimizu G., Ramanathan V., Iremonger S.

IN1 - Hydrogen Activation, Production and Storage posters

18:00 00319 The Kinetics of Dihydrogen Activation by Anti-Aromatic Boroles Houghton A.Y., Fan C., Tuononen H.M., *$Piers W.E.
18:00 00320 Biotemplating and Functionalization of Metal Oxides for Water Oxidation Bau J.A., $Buriak J.M.

IN2 - Metal Mediated Polymerization posters

18:00 00321 A Novel Synthetic Route Towards Conjugated Polymers for Solar Cells via Metallacycle Transfer *Kang L., $Rivard E.
18:00 00322 Dimerization of Ethylene by Phosphine Trifluoroborate Complexes of Palladium Gutsulyak D.V., Gott A.L., *Piers W.E.
18:00 00323 Synthesis and High Temperature Polymerization Activity of Group 4 Bidentate and Tetradentate Phenoxy-Phosphinimines Sloan M.E., $Piers W.E.
18:00 00324 Different Reasons Why O^O and P^P Chelates May Disfavor the Kinetics of Ethyl Migratory Insertion in [(X^Y)Ni(Ethyl)(Ethylne)] Compared to a Mixed P^O Chelate *$Hasanayn F., Achord P., Braunstein P., Magnier H., Krogh-Jespersen K., Goldman A.S.
18:00 00325 Anilido-aldimine Aluminum Complexes: Synthesis, Characterization and Lactide Polymerization Allan L.E.N., Bélanger J.A., Callaghan L.M., Cameron D.J.A., *Shaver M.P.
18:00 00326 Trimetallic Amine-phenolate Lithium Complexes and Their Activity in Ring-Opening Polymerization of e-Caprolactone $Ikpo N., Kerton F.M.
18:00 00327 The Synthesis and Characterization of Novel Indenylides Coordinated Group 4 Complexes Purdavaie K., *Sonnenberg J., Chibsah A., $Baird M.
18:00 00328 Organometallic-mediated Radical Polymerization: The Effects of Electronic Variance in Square-Planar Ketoaminato Cobalt Complexes Sherwood R.K., Black J.O., *$McNeil W.S.
18:00 00329 Highly Active Cu(II) Complexes as Catalysts for the Ring Opening Polymerization of Lactide $Whitehorne T.J.J., *Schaper F.
18:00 00330 Synthesis and Characterization of Bis(oxazolinylpyrrolyl)cobalt(II) Complexes for Controlled Radical Polymerization Black J.O., Sanders J.W., *$McNeil W.S.

IN4 - Ligand Design posters

18:00 00331 Organometallic and Redox Chemistry of Early Transition Metal Phthalocyanine Complexes Platel R.H., $Leznoff D.B.
18:00 00332 Multidentate Amidophosphine Ligand Design Wence D.L.K., Wong A.X., $Fryzuk M.D.
18:00 00333 New Chalcogen-Containing Bifunctional Ligands *Ritch J.S.
18:00 00334 C3-type Trinuclear Metal Complex Supported by b-Diketiminate Ligand Ogawa T., *Masuda H.
18:00 00335 Toward the Rational Design of Cooperative Ligands Wambach T.C., $Fryzuk M.D.
18:00 00336 Synthesis and Reactivity PCP Iridium Hydroxo Complexes Burford R.J., Piers W.E., *Parvez M.
18:00 00337 Complete Reduction of Carbon Monoxide Using a Dinuclear Tantalum Tetrahydride Pick F.S., *$Fryzuk M., Ballman J.
18:00 00338 Thioindigo 2,2'-diimines as Ligands for Multimetallic Complexes Boice G.N., Bohne C, Hicks R.G.
18:00 00339 Unexpected Tridentate Phosphine Oxide, Phosphine, and Mixed PhosphinePhosphine Oxide Ligands that Resemble Bis(diphenylphosphino)methane and 1,2-Bis(diphenylphosphino)ethane *Sues P.E., Lough A.J., $Morris R.H.
18:00 00340 Iron(II) Complexes for Ketone Hydrogenation Lagaditis P.O., Lough A.J., *$Morris R.H.
18:00 00341 Structure and Reactivity of Pt(II) and Pd(II) Complexes with a New trans-chelating Bis-pyridyl Ligand Wang N., McCormick T.M., *$Wang S.
18:00 00342 Functionalized Tris(pyrazolyl)borate and Tris(triazolyl)borate Ligands as Potential PARACEST MRI Contrast Agents Nicholls-Allison E., $Berg D.
18:00 00343 Utilization of Perfluoropolyalkylethers for Fluorous Biphase Systems Jelier B.J., Leznoff D.B., Montgomery C.D., *$Friesen C.M.
18:00 00344 Iminoisoindoline-based Palladium Complexes: Synthesis and Applications in Coupling Reactions Wu S.C., $Foley S.R., *Chitanda J.M.
18:00 00345 Exploiting Non-innocent Ligand Reactivity for the Synthesis of Chiral Thioether Ligands Moscattini J.E., $Fekl U.
18:00 00346 Monosulphonated (bis)phosphines for the Detection of Catalytic Intermediates Naka T.L., Vikse K.L., *McIndoe J.S.
18:00 00347 The Synthesis and Reactivity of Mixed Donor Amido-Amino-Siloxo Actinide Complexes Gill D.E., Hayes C.E., *$Leznoff D.B.

IN5 - Main Group Chemistry posters

18:00 00348 Bifunctional Pnictogens with Acid/Base Properties: Carbon Dioxide Activation Using Ring-Strained Aminophosphoranes Hounjet L.J., Caputo C.B., *$Stephan D.W.
18:00 00349 Electron-Rich Main Group Methanediides: Structures, Bonding and Insertion Products Thirumoorthi R., Chivers T., Vargas-Baca I.
18:00 00350 Novel Conjugated Inorganic Heterocycles: Synthesis and Properties He G., Kang L., Delgado W., Brandt J., Ramsay W., *$Rivard E.
18:00 00351 Synthesis and Characterization of Group 13 Complexes of Bis(pyridyl)methane Vasko P., Kinnunen V., Konu J., *Tuononen H.M.
18:00 00352 The Taming of Azidotetrazole: The Azidotetrazolate-2-Oxide Anion Klapoetke T.M., Piercey D.G., Stierstorfer J.
18:00 00353 Synthesis and Characterization of SF4 Nitrogen-Base Adducts Goettel J.T., Chaudhary P., Hazendonk P., Mercier H.P.A., *$Gerken M.
18:00 00354 Here We Glow: En Route to Luminescent Borafluorene Polymers for Nucleophile Sensing Berger C.J., Ferguson M.J., McDonald R., $Rivard E.
18:00 00355 Chiral Silicon-bridged [1]ferrocenophanes: Synthesis, Characterization and Polymerization Sadeh S., *Müller J., Harms K.
18:00 00356 Synthesis and Characterization of SF3+ Nitrogen-Bases Adducts Chaudhary P., Hazendonk P., *$Gerken M.
18:00 00357 Synthesis and Reactivity of Novel P(III)-analogues to Diimine Ligands: A Phosphinodiimine ("NPN") and an Amidinophosphaalkene ("PNN") Mokhtabad Amrei L., $Boeré R.T
18:00 00358 Electrochemical and Spectroelectrochemical Experiments on 1,2,4-Dithiazolium Salts *Boere R.T., Shotonwa I.O.
18:00 00359 Synthesis and Characterization of 4,7-dipyridinyl benzo-2,1,3-thiadiazole and its Derivatives Boere R.T., Okeh S.A.
18:00 00360 Climbing the Ladder Towards New Boron Containing Materials Araneda J.F., $Piers W.E., Parvez M.
18:00 00361 Backbone-methylated N-Heterocyclic Carbenes and their use as Lewis Bases in the Main Group McDonald S.M., Ibrahim S.M.I., McDonald R., Ferguson M.J., $Rivard E.
18:00 00362 Metal-free Dehydrogenation of Amine-boranes by N-Heterocyclic Carbenes Sabourin K.J., *McDonald R., Ferguson M., $Rivard E.
18:00 00363 Tuning Lewis Acidity: The Synthesis and Characterization of a New Fluoroaryl Borane Morgan M.M., $Piers W.E.
18:00 00364 N,C-Bound Phosphenium Cations: Synthesis and Reactivity with Small Molecules Gray P.A., *Ellis B.D.

IN6 - Solar Fuels posters

18:00 00365 Studies on the Reactions of Pt(II)-Based H2-Evolving Catalysts with H2 in Aqueous Solution Yamauchi K., *$Sakai K.
18:00 00366 Enhancing Light Absorption for Cycloruthenated Chromophores for the Dye-Sensitized Solar Cell Pogozhev D., *$Berlinguette C.P.
18:00 00367 Using a Re(I) Aza-Dipyrromethene based Complex Toward the Self-Assembly of High-Energy Light-Harvesting Antennas Bessette A., O'Connor A., Ferrera J., Bélanger F., Désilets D., *$Hanan G. S.
18:00 00368 Hydroxyamidinate Cobalt Complexes - Potential Catalysts for Hydrogen Production? Cibian M., Chartrand D., *$Hanan G.S., Tanaka S., Sakai K.
18:00 00369 Recycling of a Hydrogen Generating Photocatalyst Kastl E., Chartrand D., Laverdičre F., Rau S., Hanan G.S.

IN7 - Metal Ions in Biology posters

18:00 00370 Structural Characterization of Cd2+-DMSA and Cd2+-DMPS Complexes Zeini Jahromi E., Pickering I.J., George G.N., Gailer J.
18:00 00371 Elucidating the Antimicrobial Mechanisms of Silver: Significance of Higher Oxidation States and Reduction Potential Lischuk D., Spina C.
18:00 00372 Interaction of the Anti-Tumor Active Compound Rh2(CH3COO)4 with Amino Acids, Histidine and Methionine Niksirat P., *Jalilehvand F.
18:00 00373 Dynamic Protein Binding of cis-platin in Human Plasma In Vitro Sooriyaarachchi M., Pickering I.J., George G.N., Gailer J.
18:00 00374 Coordinating Cryptands: High-Yield Synthesis and Biomimetic Applications Chaloner L., *$Ottenwaelder X.
18:00 00375 Pentapeptides as 2+1 Chelation Systems for Re/Tc Tricarbonyl Ngo B.N., Wang W., $Luyt L.G.
18:00 00376 Determining the Effect of Hydrophobic Protein Interactions on Activity of Ruthenium(III) Anticancer Agents. Webb M.I., Chard R.A., Wu B., Wong E.W.Y., Jones M.J., Al-Jobory Y.M., $Walsby C.J.
18:00 00377 Ruthenium(III) Anticancer Drugs: From NAMI-A to Heterobimetallic Redox-active Complexes Mu C., Lewis A., Webb M.I., *$Walsby C.J.
18:00 00378 Comprehensive Evaluation of Density Functionals and Basis Sets for Uranyl Coordination Chemistry Burbank K., *$Szilagyi R.K.
18:00 00379 Counting Cysteines in Metallothionein Mahrok A.K., Summers K.L., $Stillman M.J.
18:00 00380 Hg(II) Complex Formation with N-acetylcysteine in Aqueous Solution Zielke S.A., Parmar K., *$Jalilehvand F.
INGlen 205

Diversity and Challenges of Inorganic Molecular and Materials Modelling (joint with PT7)

13:40 See PT7.

17:20 End of Session

INMacleod D

Molecular Design of Optical, Photonic and Electronic Materials (joint with MT2)

13:40 See MT2.

17:40 End of Session

INMacleod C

Symposium on Homogeneous and Heterogeneous Catalysis in Honour of Howard Alper (joint with OR2)

13:40 See OR2.

17:20 End of Session

INTELUS 108,109

Teaching Inorganic Chemistry (joint with CE4)

13:40 See CE4.

17:00 End of Session


Monday AM

IN2Macleod E3

Metal Mediated Polymerization (joint with MS)

Organizer(s) - M. Shaver, P. Hayes
Chair(s) - M. Shaver

08:20 00632 Transition Metal Amine-bis(phenolate) Complexes as Catalysts for the Copolymerization of CO2 and Epoxides to Give Poly(carbonates) *$Kozak C.M.
08:40 00633 Functional Polyolefins by Selective Ring-opening Metathesis Polymerization Hillmyer M.A.
09:20 00634 Controlled Radical Polymerization Mediated by Amine-bis(phenolate) Iron(III) Complexes Allan L.E.N., MacDonald J.P., *Shaver M.P.
09:40 00635 Synthetic and Mechanistic Advances in the Cobalt-mediated Radical Polymerization of Vinyl Amides *$Debuigne A., Hurtgen M., Liu J., Jérôme C., Detrembleur C.
10:00 Coffee Break
10:20 00636 Bis(acetylacetonato)cobalt(II) (Co(acac)2), an Efficient Spin-trap for Controlling the Radical Polymerization of Different Families of Vinyl Monomers *$Detrembleur C., Hurtgen M., Piette Y., Liu J., Jérôme C., Versace D.-L., Debuigne A.
11:00 00637 Living Radical Polymerization in Aqueous Dispersions; Advances and New Opportunities *$Cunningham M.F.
11:20 00638 Exploring the Mechanisms of Organometallic-Mediated Radical Polymerization: The Role of Ligands and Geometry Variation in Four-Coordinate Cobalt Sherwood R.K., Black J.O., *$McNeil W.S.
11:40 00639 Coordination Chemistry Affecting the Organometallic Mediated Radical Polymerization of Unreactive Monomers with Cobalt and Iron Acetylacetonates *$Poli R., Xue Z., Morin A.
12:20 End of Session

IN3Macleod E2

Symposium on the Applications of Physical Methods to Coordination Chemistry in Honour of Barry Lever

Organizer(s) - R.J. Crutchley
Chair(s) - S.I. Gorelsky, R.J. Crutchley

08:00 00640 PCET in Ground and Excited States *$Meyer T.J., Gagliardi C.J., Stewart D., Binstead R.A., Murphy C.F., Murphy G.S., Song N., Thorp H.H.
08:40 00641 Aspects of Electron Transfer Reactions in trans-[Ru(NO)L1L2]n+ $Metzker G., *Franco D.W.
09:20 00642 Phototriggering Electron Flow In Azurins With a ReI(CO)3(phenanthroline)-Tryptophan Unit Vlcek A., Blanco-Rodriguez A.B., Zalis S., Gray H.B.
10:00 Coffee Break
10:20 00643 Geometric and Electronic Structure Contributions to Cu/O2 Reactivity Solomon E.I.
11:00 00644 Ruthenium Nitrosyls as Nitric Oxide Donors Tfouni E.
11:40 00645 Physical Methods in Medicinal Inorganic Chemistry *$Orvig C., Cawthray J., Adam M.J., Price E.W., Ramogida C., Boros E.
12:20 End of Session

IN4Macleod E1

Ligand Design (joint with OR)

Organizer(s) - S. Johnson, T. Storr
Chair(s) - T. Storr, L. Turculet

08:00 00646 Chiral Multidentate Ligands for Olefin Polymerization Etkin N., Green J.D.
08:20 00647 Electron-hole Localization in a Series of Symmetric Nickel(II) Salen Ligand Radical Complexes Chiang L., Kochem A., Jarjayes O., Dunn T., Storr T., $Thomas F.
08:40 00648 Making New Ligands in the Coordination Sphere of a Metal: Addition Reactions to Metal-coordinated Dithiolenes *$Fekl U.
09:00 00649 Diamidosilylether Ligands and their Retro-Brook Re-arranged Analogues: Chemistry from Lithium to Uranium *Leznoff D.B.
09:20 00650 2,2',6',2''-Terpyridine: a Redox-active Ligand in Coordination Chemistry *Wieghardt K.E., Scarborough C.C.
10:00 Coffee Break
10:20 00651 Di-N-Heterocyclic Carbenes, Di-Mesoionic Carbenes, and Hybrid Versions Thereof as Bridging Frameworks for Mixed-Metal Dinuclear Complexes Zamora M.T., Ferguson M.J., McDonald R., *$Cowie M.
10:40 00652 Structures and Chemical Reactivity of Binuclear Palladium Complexes with N,S,S,N-Ligands Containing the ortho-Aminothiophenol Motif Acosta J.A.R., Cross E.D., MacDonald K., *$Bierenstiel M.
11:00 00653 Tripodal Complexes Containing Pendant Amines for Dioxygen Activation Blacquiere J.M., Forget A., $Mayer J.M.
11:20 00654 A Functional Oxotransferase Model from a Molybdenum Tris(dithiolene) Complex by Nucleophilic Addition to the Ligand Nguyen N., Armstrong D., *$Fekl U.
11:40 00655 Synthetic Models of the Oxygen Evolving Complex of Photosystem II *$Agapie T., Kanady J.S., Tsui E.Y.
12:20 End of Session

INGlen 205

Diversity and Challenges of Inorganic Molecular and Materials Modelling (joint with PT7)

08:00 See PT7.

12:20 End of Session

INMacleod D

Molecular Design of Optical, Photonic and Electronic Materials (joint with MT2)

08:00 See MT2.

12:20 End of Session

INMacleod C

Symposium on Homogeneous and Heterogeneous Catalysis in Honour of Howard Alper (joint with OR2)

08:00 See OR2.

12:20 End of Session


Monday PM

IN3Macleod E2

Symposium on the Applications of Physical Methods to Coordination Chemistry in Honour of Barry Lever

Organizer(s) - R.J. Crutchley
Chair(s) - R.J. Crutchley

13:40 00888 Metallocenyl-containing Porphyrins, Tetraazaporphrins, and Subphthalocyanines: What Did We Learn So Far? *$Nemykin V.N.
14:20 00889 Relationship between the Molecular Structures and Spectroscopic and Electrochemical Properties of Azaporphyrinoids *$Kobayashi N.
15:00 00890 Ruthenium(II) Complexes with Sulfur-Containing Ligands: Potential Models for Heme Proteins *$James B.R., Reboucas J.S., Ma E.S.F.
15:40 Coffee Break
16:00 00891 Relating Spectral Properties of Porphyrins and Phthalocyanines to Theoretical Parameters from their Electronic Structures *$Stillman M.J., Kwan L., Jeffs K., Deshpande R., Deng Y., Jiang L., Wang H.
16:20 00892 Origins of Regioselectivity of the Palladium-Catalyzed (Aromatic)C-H Bond Metalation-Deprotonation *$Gorelsky S.I.
16:40 00893 Coordination Chemistry of Heteroditopic Ligands Containing an N-Heterocyclic Carbene or a Derivative Thereof, and Catalytic Activity of the Corresponding Complexes *$Lavoie G.G.
17:00 00894 Electrospray Ionization Mass Spectrometry for the Real-Time Analysis of Catalytic Reactions Ahmadi Z., Vikse K.L., Yunker L., Logan J., Naka T., *$McIndoe J.S.
17:20 End of Session

IN4Macleod E1

Ligand Design (joint with OR)

Organizer(s) - S. Johnson, T. Storr
Chair(s) - D. Song, M. Zamora

13:40 00895 Exploiting Silicon in Ligand Design: Novel Structure and Reactivity Involving Silyl Pincer Complexes of the Platinum Group Metals *$Turculet L.
14:00 00896 New DalPhos Ligands for Use in Palladium-Catalyzed Indole Synthesis Lavery C.B., $Stradiotto M.
14:20 00897 Redox-Active Ligands for Unconventional C-X Activation Zhu D., *$Budzelaar P.H.M.
14:40 00898 Planar Chiral Ruthenium Complexes of Phosphonium Indenylide (PHIN) Ligands Fowler G.K., Hussian R., $Baird M.C.
15:00 00899 Reaction Chemistry Stemming from Cobalt Tris-m-Terphenylisocyanide Complexes *$Figueroa J.S., Carpenter A.E., Millard M.D.
15:20 00900 Nindigo: Adventures in Bridging Ligand Design *Hicks R.G., Nawn G.
15:40 Coffee Break
16:00 00901 Triazine-based Bridging Ligands for the Assembly of Transition Metal-based Extended Networks and Porous Frameworks Pizarro-Cartier E., Thompson R., Reid D., Cull J.E.W., *$Scott J.
16:20 00902 Polymerization and Applications of Chiral Phosphaalkenes Serin S.C., Gates D.P., $Dake G.R.
16:40 00903 Diamido-Actinide Complexes as Catalysts for Intramolecular Hydroamination Hayes C.E., Platel R.H., $Leznoff D.B., *Schafer L.L.
17:00 00904 Alternate Routes for the Synthesis and Coordination of Substituted Benzotriazolium Cations Poisson J., Bain C.D., $Butler I.S., *Bohle D.S.
17:20 End of Session

IN6Macleod B

Solar Fuels (joint with MT)

Organizer(s) - C. Berlinguette, G. Hanan
Chair(s) - C. Berlinguette, G. Hanan

13:40 00905 Integrating Photoconversion with Catalysis for Artificial Photosynthesis *$Wasielewski M.R. WITHDRAWN
14:20 00906 Photoelectrochemistry of Hematite for Water Splitting *$Hamann T.W., Klahr B.
14:40 00907 Molecular Complexes for Water Activation *$Aukauloo A., El Ghachtouli S., DinhNguyen M.T.
15:00 00908 New Electrocatalysis for Oxygen Chemistry *Mayer J.M., Barnett S.M., Waidmann C.R., Carver C.T., Matson B.D., Tronic T.A., Blacquiere J.M.
15:40 Coffee Break
16:00 00909 Cobalt-based Catalysts for Water-splitting *$Artero V.
16:40 00910 Better Water Oxidation with Hematite: An ALD Approach *$Martinson A.B.F., DeVries M.J., Riha S.C., Hupp J.T., Pellin M.J.
17:00 00911 Proton-Coupled Electron Transfer in Catalyzed Electrochemical Reduction of CO2 *$Saveant J.M. WITHDRAWN
17:40 End of Session

IN8Glen 206

General

Organizer(s) - R. Roesler
Chair(s) - D.B. Leznoff

Rio Tinto Alcan Award lecture:

13:40 00912 Metal-Organic Framework (MOF) Materials with Dynamic Interlocked Components Loeb S.J.
14:20 00913 Reductive Elimination of Halogen from [AuX2(CN)2]- Units: Toward Au(I)-based Coordination Polymers Ovens J.S., *$Leznoff D.B.
14:40 00914 Metal-Ligand Self-Assembly with Rotaxanes Viljoen E., *$Loeb S.J.
15:00 00915 Synthesis and Characterisation of Discrete Multimetallic Assembly Laramée B., *K. Pal A.
15:20 00916 A [3+3] Neutral Metal Self-assembly Approach to Novel Ensembles Pal A.K., $Hanan G.S., *Hasenknopf B.
15:40 Coffee Break
16:00 00917 Nanocrystalline Cellulose: A Novel Template for Mesoporous Materials Shopsowitz K.E., Hamad W.Y., $MacLachlan M.J., *Qi H.
16:40 00918 New Rotaxane Ligands with Donors on Both the Axle and Wheel Frank N.C., Loeb S.J.
17:00 00919 Cyclometallated Iridium Complexes with Unique Structural Properties for Applications in Molecular Motors Howarth A.J., $Wolf M.O., Davies D.L., *Lelj F.
17:20 End of Session

INGlen 205

Diversity and Challenges of Inorganic Molecular and Materials Modelling (joint with PT7)

13:40 See PT7.

17:20 End of Session

INMacleod D

Molecular Design of Optical, Photonic and Electronic Materials (joint with MT2)

13:40 See MT2.

17:40 End of Session

INMacleod C

Symposium on Homogeneous and Heterogeneous Catalysis in Honour of Howard Alper (joint with OR2)

13:40 See OR2.

17:20 End of Session


Tuesday AM

IN5Macleod E3

Main Group Chemistry

Organizer(s) - E. Rivard
Chair(s) - J. Masuda

08:00 01189 Coordination Chemistry Approaches to Non-metal Element-Element Bond Formation *$Burford N., Chitnis S.S., MacDonald E.
08:40 01190 Tamed Silicon Cation: Characterization and Catalysis *Oestreich M., Müther K., Schmidt R.K., Klare H.F.T.
09:00 01191 Iron-Catalysed Dehydrocoupling/Dehydrogenation of Amine-Borane Adducts: Formation of Boron-Nitrogen Oligomers and Polymers Vance J.R., Robertson A.P.M., Lee K., *Manners I.
09:20 01192 Formation of Hybrid Hexahalidotellurate Anions. Structural, Spectroscopic, and Computational Identification of cis-isomers of [TeBr2Cl4]2- and [TeCl2Br4]2- Narhi S.M., Kutuniva J., Lahtinen M.K., Tuononen H.M., Oilunkaniemi R., *$Laitinen R.S.
09:40 01193 Structural Diversity and Reactivity of Phosphine-stabilized Antimony Cations *Chitnis S.S., $Burford N.
10:00 Coffee Break
10:20 01194 Lewis Acidic Properties of Heavy Group 15 and 16 Elements Toward Transition Metals Lin T.-P., Ke I.-S., Wade C.R., *$Gabbai F.P.
11:00 01195 Germanium and Mixed Germanium/Tin Oligomers $Weinert S., Roewe K., Schrick E., *Schrick A.
11:20 01196 An Approach towards Asymmetrically Bridged [1.1]Ferrocenophane Bagh B., Breit N.C., Dey S., Gilroy J.B., Harms K., Schatte G., $Müller J.
11:40 01197 Borane-Appended Late Transition Metal Complexes *$Emslie D.J.H., Cowie B.E., Kolpin K.B., Parker K.D., Oakley S.R.
12:00 01198 Modifying the Properties of N-heterocyclic Carbenes by the Incorporation of Phosphorus and Sulfur Functionalities Borau Garcia J., Forster T.D., Hiranandani R., Palakodeti S.R., Mahrok A., Tuononen H.M., *$Roesler R.
12:20 End of Session

IN6Macleod E4

Solar Fuels (joint with MT)

Organizer(s) - C. Berlinguette, G. Hanan
Chair(s) - F.N. Castellano, L. Spiccia

08:00 01199 Bioinspired Manganese Water Oxidation Catalysis Spiccia L.
08:40 01200 Fast and Robust Molecular Water Oxidation Catalysts *Bernhard S., Lalrempuia R., Woods J.A., Petronilho A., McDaniel N.D., $Albrecht M.
09:00 01201 Cobalt Platforms for Investigating Proton-Coupled Electron Transfer and Catalytic Water Oxidation Wasylenko D.J., Palmer R.D., *$Berlinguette C.P.
09:20 01202 A Supramolecular Approach to Artificial Photosynthesis Campagna S., Puntoriero F., Nastasi F., La Ganga G.
10:00 Coffee Break
10:20 01203 Chemical, Electrochemical and Photochemical Water Oxidation by Highly Efficient Molecular Catalysts and Mechanisms for O-O Bond Formation *$Sun L., Fei L., Privalov T., Duan L., Tong L., Xu Y. WITHDRAWN
11:00 01204 Water Oxidation Mechanism with Ruthenium Complexes: Direct Pathway via Ru(IV) Oxo Species Polyansky D.E., Muckerman J.T., Badiei Y., Haberdar R., Zong R., Thummel R.P., *$Fujita E.
11:20 01205 PCET in Ground and Excited States *$Meyer T.J., Gagliardi C.J., Stewart D., Binstead R.A., Murphy C.F., Murphy G.S., Song N., Thorp H.H.
11:40 01206 Photo-assisted Catalyst Growth and Water Splitting at the Metal Oxide/Molecule Interface Castellano F.N.
12:00 01207 Mechanistic Aspects of Catalytic Water Oxidation *Privalov T.
12:20 End of Session

IN7Macleod E2

Metal Ions in Biology (joint with BM)

Organizer(s) - F. Jalilehvand, J. Gailer
Chair(s) - F. Jalilehvand, P. Kennepohl

08:00 01208 X-Ray Spectroscopic Studies of Biological Dinitrogen Reduction *DeBeer S.
08:40 01209 Contribution of Electrostatics to Cobalt-Carbon Bond Homolysis in Adenosylcoblamain-dependent Enzymes Makins C., Mariani C., *$Wolthers K.R.
09:00 01210 X-ray Absorption Spectroscopic Studies of Mo and W Enzymes Pushie M.J., Cotelasage J., *$George G.N.
09:20 01211 Tag Team: PhnY and PhnZ Comprise a New Enzyme Mechanism for Oxidative Cleavage of a Carbon Phosphorous Bond McSorley F.R., Wyatt P.B., Martinez A., DeLong E.F., *$Zechel D.L., Hove-Jensen B.
09:40 01212 Activation of the Nickel-responsive Transcription Factor NikR *$Zamble D.B., Li Y., Wang S.C., Krecisz S., Jones M., Ademi I.
10:00 Coffee Break
10:20 01213 Chloroquine and Mefloquine Ferrocenyl Conjugates for the Treatment of Malaria *$Orvig C., Salas P.F., Herrmann C., Cawthray J., Adam M.J.
10:40 01214 The Metal-Requirement of Anthrax Lethal Factor: A Bioinorganic Perspective $Siemann S.
11:00 01215 Linking Synchrotron X-ray Fluorescence and Clinical Imaging to Detect and Quantify Brain Iron in Stroke *$Nichol H., Zheng W., Haacke E.M.
11:20 01216 Facile Me2As-Thiol Transfer and Lability: Consequences to Acute Promyelocytic Leukemia Drug Therapy Gu Y., $Bohle D.S.
11:40 01217 Chronic Toxicity of AsIII in Humans: the Role of (GS)2AsSe- *Gailer J., George G.N., Pickering IJ.
12:00 01218 Understanding Chemical Interactions Between Heavy Metals (Hg, Pb, Bi) and Amino Acids *$Burford N., Saunders C.D.L., Phillips H.A.
12:20 End of Session

IN8Glen 201

General

Organizer(s) - R. Roesler
Chair(s) - L. Rosenberg

08:00 01219 Structure and Reactivity of Bio-Inspired Metal-Arylnitroso Complexes *$Ottenwaelder X.
08:20 01220 Cheating Death in Ru-Catalyzed Olefin Metathesis: Direct Studies of Ru-methylidene Species Lummiss J., $Fogg D.E.
08:40 01221 Further Insights on N,N'-Disubstituted Hydroxyamidines and Their Metallic Complexes Cibian M., Langis-Barsetti S., Bisiaux L., Long Nguyen P., *$Hanan G.S.
09:00 01222 Mechanistic Insights into [2+2]-Cycloadditions at a Ruthenium-Phosphorus p-Bond Morrow K., Pantazis D., McDonald R., $Rosenberg L.
09:20 01223 Chemistry of Nindigo Coordination Complexes $Nawn G., *Hicks R.G.
09:40 01224 Tuning "Umbrella" Ligands to offer Different Shades of Protection to Group IV Metal Complexes. Lummis P.A., Al-Rafia S.M.I., Liew S.K., Miedema L.J., McDonald R., Ferguson M.J., *$Rivard E.
10:00 Coffee Break
10:20 01225 Reactivity of Cr(III) l-Oxo Complexes: Catalyst Regeneration and Atom Transfer Processes MacLeod K.C., *$Smith K.M.
10:40 01226 Synthesis and Reactivity Differences of Bridged and Non-Bridged Dinuclear Pt/Mn Complexes with Thiiranes and Thietanes Zamora M.T., Oda K., Zhao S., Komine N., Hirano M., *$Komiya S.
11:00 01227 Reactivity of CO2 With Scandium b-Diketiminate and Anilido-Pyridylquinoline Alkyl Complexes $Piers W.E., LeBlanc F.A., Berkefeld A., Parvez M.
11:20 01228 Coordination Chemistry and CO2 Activation by Copper Complexes Supported by Amidine and Phosphamidine Ligands *Huynh K., Dalgliesh L., Wang R., $Jessop P.
11:40 01229 Water Solube and Stable Sulfonated N-Heterocyclic Carbene Complexes Hiranandani R.R., Forster T.D., Mahrok A.K, Mensik N., $Roesler R., Enright G.
12:00 01230 Pd(g3-1-Ph-C3H4)(g5-C5H5), a Preferred Precatalyst for Cross-Coupling Reactions Catalyzed by Bis-phosphine Palladium(0) Compounds Fraser A.W., $Baird M.C.
12:20 End of Session

INMacleod D

Molecular Design of Optical, Photonic and Electronic Materials (joint with MT2)

08:00 See MT2.

12:20 End of Session


Tuesday PM

IN5Macleod E3

Main Group Chemistry

Organizer(s) - E. Rivard
Chair(s) - P. Ragogna

13:20 01451 The Synthesis and Reactivity of Metallocene-Substituted a-diimine Ligands Magdzinski E., Ragogna P.J.
13:40 01452 Stable Neutral Tricoordinate Organoboron Derivatives Isoelectronic with Amines Bertrand G.
14:20 01453 Merging the Chemistry of Electron-Rich Olefins (ERO) with Imidazolium Ionic Liquids Sherren C.N., Mu C., Webb M.I., McKenzie I., McCollum B.M., Brodovitch J.-C., Percival P.W., Storr T., Seddon K.R., *Clyburne J.A.C., Walsby C.J.
14:40 01454 Oxophilic Heterocyclic Phosphenium Cations Hendsbee A.D., Giffin N.A., *$Masuda J.D.
15:00 01455 Asymmetric Dicoordinate Phosphorus(III) Cations: Synthesis and Reactivity with Hydrogen Gray P.A., Koncovy V.J., *Ellis B.D.
15:20 01456 Tetraelphosphonium Salts $MacDonald E.P., *Burford N., Werner-Zwanziger U., Decken A.
15:40 Break

16:00 01457 Disilenes and Digermenes as Molecular Models for the Reactivity of Dimers on Si- and Ge(100)-2x1 Surfaces *$Baines K.M.
16:40 Coffee Break
17:00 End of Session

IN7Macleod E2

Metal Ions in Biology (joint with BM)

Organizer(s) - F. Jalilehvand, J. Gailer
Chair(s) - D. Zamble, T. Storr

13:40 01458 New Adventures in Phosphorylation Chemistry Kraatz H.-B.
14:00 01459 Genetic Material Interaction and Cleavage Using Copper Complexes: An Underpinning Step to Breast Anti-Proliferative Study Subramani R., *Balachandran U.N.
14:20 01460 Evaluation of the Interaction of Metal Ions (Pt, Ru, Re, Tc, Zn, Cd, Cu, Pb) with Proteins and DNA by ESI-TOF MS *Palacios Ň., Atrian S., $Capdevila M.
14:40 01461 Reaction Pathways of Ru(III) Anticancer Prodrugs *$Walsby C.J., Al-Jobory Y.M., Mu C., Webb M.I.
15:00 01462 Evaluating the Role of Ru-S Bonding in Defining the Biological Mechanism of Ru Arene Anticancer Agents Sriskandakumar T., Petzold H., Bruijnincx P.C. A, Habtemariam A., Sadler P.J., *$Kennepohl P.
15:20 01463 Rh(II) Acetate Complexes with Thiol Containing Ligands *$Jalilehvand F., Niksirat P.
15:40 Break

16:00 01464 Methylmercury and Sensory Organs: Linking Uptake with Functional Deficits in Developing Vertebrates Korbas M., MacDonald T.C., Sylvain N.J., Pickering I.J., George G.N., Krone P.H.
16:20 01465 Interactions of Cadmium with Iron and Zinc in Freshwater Fish: Uptake and Metabolism *Niyogi S., Kwong R.
16:40 Coffee Break
17:00 End of Session

INGlen 201

Solid State Chemistry (joint with MT4)

13:40 See MT4.

16:40 End of Session


Wednesday AM

IN1Macleod E1

Hydrogen Activation, Production and Storage

Organizer(s) - R.T. Baker, D. Stephan
Chair(s) - D.W. Stephan

08:00 01726 Electronic Aspects of H2 Splitting by d6 Ru-amides *$Hasanayn F., Morris R.H.
08:20 01727 Catalytic Redistribution and Polymerization of Diborazanes: Unexpected Observation of Metal-Free Aminoborane Hydrogenation Robertson A.P.M., Leitao E.M., *Manners I.
08:40 01728 Metal-Free Aromatic Hydrogenations *$Stephan D.W., Mahdi T., Grimme S.
09:00 01729 Enantioselective Catalysis with Chrial Frustrated Lewis Pairs Chen D., Ghattas G., Hölscher M., Klankermayer J.
09:20 01730 Homogeneous Hydrogenations with Rhenium Complexes Revealing Performances Superior to Precious Metal Catalysts Dudle B., Jiang Y., Kunjanpillai R., Blacque O., Fox T., *$Berke H.
10:00 Coffee Break
10:20 01731 Design and Development of Molecular Electrocatalysts for Production of Hydrogen: Shoving Protons Around With Proton Relays *$Bullock R.M., Kilgore U.J., Helm M.L., Roberts J.A., DuBois D.L.
11:00 01732 Microbial Paths to Renewable Hydrogen Hallenbeck P.C., Abo-Hashesh M., Liu Y., Ghosh D.
11:20 01733 Metal-Free Arene Hydrogenation of Anilines and N-Heterocyclic Compounds Utilizing Frustrated Lewis Pairs Mahdi T., $Stephan D.W.
11:40 01734 Photochemical Molecular Devices for Light Driven Water Splitting and Hydrogenation of Organic Substrates Rau S.
12:00 01735 Production of H2 Using Molecular Devices for Photochemical or Electrochemical Reduction of Water *Brewer K.J., White T., Manbeck G., Knoll J., Whitaker B., Arachchige S., King S., Mallalieu H.
12:20 End of Session

IN5Macleod E3

Main Group Chemistry

Organizer(s) - E. Rivard
Chair(s) - E. Rivard

08:00 01736 On the Way to Pure Phosphorus Cations *$Krossing I.
08:40 01737 Planar P6E6 (E = S, Se) Macrocycles Incorporating P2N2 Scaffolds Nordheider A., Chivers T., Thirumoorthi R., Vargas-Baca I., Woollins J.D.
09:00 01738 Recent Progress in SF4 Chemistry Chaudhary P., Goettel J.T., Hazendonk P., Mercier H.P.A., *$Gerken M.
09:20 01739 Synthesis of New Group 13 Dihalides, Metallocenophanes and Metallopolymers Breit N.C., $Müller J., Harms K.
09:40 01740 Optical and Electronic Properties of Tellurophenes with Delocalized p-Systems and Their Extended Valence Adducts McCormick T.M., Kapp M.J., Jahnke A.A., *$Seferos D.S.
10:00 Coffee Break
10:20 01741 Surprises from Zwitterionic Silylenes and Germylenes with Respect to Small Molecule Activation Driess M., Yao S., Stoelzel M., Praesang C.
11:00 01742 Carbene Complexes of Low-Valent Phosphorus Cations *$Macdonald C.L.B.
11:20 01743 Organoboron-Functionalized N-Heterocyclic Carbene Compounds *$Wang S., Rao Y.L., Amarne H., Chen L., Lu J.S., Hudson Z.M.
11:40 01744 Hypervalent 4c-6e Radical s-Dimers and their Response to Physical Pressure - Mother Nature Knows Best Lekin K., Wong J., Leitch A.A., Tse J.S., Laniel D., Desgreniers S., Secco R.A., *Oakley R.T.
12:00 01745 Towards More Stable Group 13 Carbene Analogues Bates J.I., $Aldridge S.
12:20 End of Session

IN6Macleod E4

Solar Fuels (joint with MT)

Organizer(s) - C. Berlinguette, G. Hanan
Chair(s) - G. Hanan, S. Campagna

08:00 01746 Novel Supramolecular Photocatalysts Based on NHC-Ligands Rau S., Pilz T.D.
08:40 01747 Homogenous Photocatalytic Hydrogen Evolution from Water under Acidic Conditions Guttentag M., $Alberto R., Rodenberg A., Hamm P.
09:00 01748 Hydrogen Production Studies of Photo-Catalytic Systems Based on Ruthenium and Rhenium Chromophores Chartrand D., Randell N., *Hanan G.S.
09:20 01749 Designing Supramolecular Complexes for Conversion of Solar Energy *Brewer K.J., White T., Manbeck G., Knoll J., Zhou R., Quinn K., Whitaker B., Arachchige A., King S., Dent E., Mallalieu H.
10:00 Coffee Break
10:20 01750 Water Splitting Reactions Catalyzed by Transition Metal Complexes Sakai K.
11:00 01751 The Development of Structure/Function Relationships for Solar Driven Hydrogen Generating Photocatalysts Singh Bindraa G., Soman S., Paul A., Schulz M., Pryce M.T., Rau S., *$Vos J.G.
11:40 01752 Photocatalytic CO2 Reduction with High Turnover Frequency and Selectivity of Formic Acid Formation using Ru(II) Multinuclear Complexes *Ishitani O.
12:20 End of Session

IN7Macleod E2

Metal Ions in Biology (joint with BM)

Organizer(s) - F. Jalilehvand, J. Gailer
Chair(s) - R. Szilagyi, J. Gailer

08:20 01753 Utilization of an Alzheimer's Disease Hallmark for the Generation of Therapeutic Molecules *$Storr T., Jones M.R.
08:40 01754 Development of Potential Alzheimer's Disease Therapeutics: Utilization of a Disease Hallmark Jones M.R., $Storr T.
09:00 01755 Copper, Iron, the Prion Protein, and the Amyloid Beta Peptide in Alzheimer's Disease Azimi S., *$Rauk A.
09:20 01756 Toward Development of Novel Chelators as Potential Drugs for Alzheimer's Disease Telpoukhovskaia M.A., Rodríguez-Rodríguez C., Cawthray J.F., Patrick B.O., $Orvig C.
09:40 01757 Thioflavin-based Compounds and their Multifunctional Properties for Potential Application in Alzheimer's Disease Rodriguez-Rodriguez C., Telpoukhovskaia M., *Orvig C.
10:00 Coffee Break
10:20 01758 Metal Binding Domain Structures in Metallothioneins *$Stillman M.J., Sutherland D.E.K., Summers K.L.
10:40 01759 Metallothioneins: From Zn-thioneins to Cu-thioneins Atrian S., *Capdevila M.
11:00 01760 An Exogenous Ligand Requirement for Bacterial Nickel Transport Chivers P.
11:20 01761 Metalloproteomics for Marine Cyanobacteria *$Blindauer C.A., Barnett J.P., Scanlan D.J.
11:40 01762 Molecular Basis of High Valent Uranium Toxicity in Bacteria Burbank K., Holzwarth C., Flansburg C., *$Szilagyi R.K.
12:00 01763 Quantitative Determination of Copper(II) Mobility in Wood: Evaluating Copper-based Biocides in Treated Lumber Xue W., Ruddick J.R., *$Kennepohl P.
12:20 End of Session

IN8Glen 206

General

Organizer(s) - R. Roesler
Chair(s) - R. Roesler

08:00 01764 Twisted-planar Conformation of Piperazine Ring in a Quadruple Stranded Helicate *$Chand D.K.
08:20 01765 pH Triggered Crown Ether Analogues for Alkali Earth Ion Binding Yan Y., Zhao W., Faurie A., Bhagavathy G., *$Petitjean A.
08:40 01766 Reversible sp2 C-H Bond Activation of Fumarates by Cp*Co(I) Arene Complexes Hung-Low F., Cheng S., *$Bradley C.
09:00 01767 Zirconium Catalyzed Stereoselective Enyne Synthesis: Mechanistic Investigations and Applications in Synthesis Platel R.H., Schafer L.L.
09:20 01768 NOVA Chemicals Technical Scale Facilities: Bridging the Gap *Henderson L.D.
09:40 01769 Mechanistic Investigations of a Copper- and Enamine-catalyzed Aldehyde Arylation Reaction Van Humbeck J.F., Allen A.E., $MacMillan D.W.C.
10:00 Coffee Break
10:20 01770 Thermally Stable Rare Earth Dialkyl Complexes Supported by a Novel Bis(phosphinimine)pyrrole Pincer Ligand *$Hayes P.G., Johnson K.R.D., Hannon M.A., Ritch J.S.
10:40 01771 Towards Rational Synthesis of Sintering Resistant Supported Cobalt Fischer-Tropsch Catalysts $Eggenhuisen T.M., Munnik P., Friedrich H., Nudelman F., Zecevic J., Sommerdijk N.A.J.M., de Jongh P.E., *de Jong K.P.
11:00 01772 Impact of Pendant Donors on the Stability of Titanium Phosphinimide Complexes in a High Temperature Solution Polymerization Process Morrison D.
11:20 01773 Boron: Current and Developing Markets *$Cook K.S., Manning D.
11:40 01774 Amine-Boranes and Aminoboranes as Reactive Intermediates in the Formation of Polyaminoboranes *Leitao E.M., Robertson A.P.M., Stubbs N.E., Lloyd-Jones G.C., $Manners I.
12:00 01775 Metalloradicals Based on Group 6 Piano-Stool Complexes van der Eide E.F., Liu T., Yang P., Walter E.D., Helm M.L., *Bullock R.M.
12:20 End of Session

INGlen 201

Solid State Chemistry (joint with MT4)

08:00 See MT4.

12:20 End of Session


Wednesday PM

IN1Macleod E1

Hydrogen Activation, Production and Storage

Organizer(s) - R.T. Baker, D. Stephan
Chair(s) - S. McGrady

13:40 01883 Hydrogen Storage in Nanoporous Materials: From Material's Structure to System Design Chahine R., Benard P., Dundar E., Ubaid S., Xiao J.
14:00 01884 Hydride-Hydride Bonding in Molecular and Complex Metal Hydrides: A Counterintuitive Hydrogen Release Pathway! *McGrady G.S., Che F.N., Traboulsee K.T., Titah J.T., $Wolstenholme D.J.
14:20 01885 Spectroscopic Identification of Hydrogen Spiltover onto Carbon Supports *$Gennett T., Blackburn J., Parilla P., Engtrakul C., Bult J., Hurst K., Brown C., Jensen C.
14:40 01886 A New Perspective of Hydrogen Storage Materials Study using High-Pressure Techniques *$Song Y.
15:00 01887 Novel Anode Materials for the Production of Hydrogen using CuCl/HCl Electrolyzers Edge P., $Easton E.B.
15:20 01888 Design of New Metal Nanocomposites for Hydrogen Storage and In-Situ Study of Nucleation Processes *$Urban J.J., Jeon K.J., Moon H.R., Ruminski A.M., Jiang B., Kisielowski C., Bardhan R., Hedges L.O., Whitelam S., Pint C.L., Javey A.
15:40 Coffee Break
16:00 01889 Development of a Single-Component Liquid-Phase Hydrogen Storage Material *$Liu S.-Y., Luo W., Campbell P.G.
16:20 01890 A Ligand-Metal Bifunctional Approach to Ammonia Borane Dehydrogenation *$Williams T.J., Conley B.L., Lu Z.
16:40 01891 Reactivity of a BN Ethylcyclobutane Analog: Controlling the Second Equivalent of H2 Release from Ammonia-Borane *$Baker R.T., Kalviri H., Gaertner F.
17:00 01892 Development of a Generic Mechanism for the Dehydrocoupling of Amineboranes: A Stoichiometric, Catalytic and Kinetic Study of H3BˇNMe2H using the [Rh(PCy3)2]+ Fragment *$Weller A.S., Lloyd-Jones G.C., Sewell L.J.
17:20 End of Session

IN5Macleod E3

Main Group Chemistry

Organizer(s) - E. Rivard
Chair(s) - B. Ellis

13:20 01893 Scanning and Fourier Transform Voltammetry Studies of The Oxidation of Arylpnictophanes and EPR Spectroelectrochemistry *$Boeré R.T., Taghavikish M., Roemmele T.L., Bullock J., Bond A.M.
13:40 01894 Zwitterionic Main Group Complexes Supported by Phosphinoborate Ligands Dube J.W., *$Ragogna P.J.
14:20 01895 Time-resolved Spectroscopic Studies of Low-Valent Group 14 Compounds in Solution. The Silicon, Germanium, and Tin Analogs of Diphenylcarbene *$Leigh W.J., Kostina S.S., Duffy I.
14:40 01896 Isolation of Heavy Ethylene Analogues in the Form of Donor-Acceptor Adducts *Al-Rafia S.M.I., Ferguson M.J., McDonald R., $Rivard E.
15:00 01897 Terphenyl-stabilized Group 13/14 Elements as Ligands for Transition Metal Carbonyls Caputo C.A., Fettinger J.C., *$Power P.P.
15:20 01898 Theoretical Analysis of Bonding in Tetrylene-Isocyanide Complexes Brown Z.D., Power P.P., Vasko P., *Tuononen H.M.
15:40 Coffee Break
16:00 01899 P=C Bonds in Polymer Science and Catalysis *$Gates D.P., Hey T., Hsieh T., Serin S., Siu P.
16:40 01900 Mono- and Binuclear Organoindium Thiolate Complexes and their Reactivity as Catalysts in Lactone Polymerization *$Briand G.G., Decken A., Marks J.D., Wareham R.G.
17:00 01901 Lanthanide Coordination Complexes of Thiazyl Radical Ligands *$Preuss K.E.
17:20 01902 Bottleable H2BNH2: Room Temperature Stabilization of Inorganic Ethene, a Potential Molecular Precursor for Boron Nitride (BN) *Malcolm A.C., Sabourin K.J., McDonald R., Ferguson M.J., $Rivard E.
17:40 End of Session

IN6Macleod E4

Solar Fuels (joint with MT)

Organizer(s) - C. Berlinguette, G. Hanan
Chair(s) - K. Sakai

13:40 01903 Synthesis and Chemistry of Well-Defined Monomeric Iridium and Platinum Hydroxides *$Piers W.E., Burford R.J., Lohr T.L., Parvez M.
14:00 01904 Oligothienyl(diimine)-containing Metal Complexes for Photochemical Energy Conversion *Majewski M.B., MacDonnell F.M., $Wolf M.O.
14:20 01905 Photochemical Synthesis of a Water Oxidation Catalyst Based on Cobalt Nanostructures Wee T.L., Sherman B.D., Gust D., Moore A.L., Moore T.A., $Scaiano J.C.
14:40 01906 Designing Electronic/Ionic Conducting Membranes for Artificial Photosynthesis *$Freund M.S., McFarlane S.L., McDonald M., McEleney K., Yahyaie I., Oliver D.R., Thomson D.J.
15:00 01907 CO2 Reduction by Frustrated Lewis Pairs *$Stephan D.W., Neu R.C., Doemer J., Menard G., Dobrovetsky R.
15:20 01908 Photochemical Production of H2 from Water using Ruthenium Polypyridyl Photosensitizers and Cobalt Glyoximato Catalysts Dares C., Fournier R., *$Lever A.B.P.
15:40 Coffee Break
16:00 01909 Intermediates in Pd Complex-catalyzed Hydrogen Production from Protons *$Baker R.T., Gaunt A.J., Dehestani A., Scott B.L., Kubas G.J., Roy L., Batista E., Thomas J.
16:20 01910 Oxygen Evolution from Water Catalyzed by Metal Complexes: Reaction Mechanism and Catalyst Design *$Masaoka S.
16:40 01911 2D Electronic Spectroscopy of Natural Light-Harvesting Complexes Reveals a Dark Carotenoid State Mediating Carotenoid-to-Bacteriochlorophyll Energy Transfer Ostroumov E.E., $Scholes G.D.
17:00 End of Session

IN8Glen 206

General

Organizer(s) - R. Roesler
Chair(s) - P. Hayes

13:40 01912 Late Transition Metal Vinylborane Complexes *$Emslie D.J.H., Kolpin K.B., Thompson J.
14:00 01913 Towards Commerciallization of Chemistry: A Case Study with Metal-free Hydrogenation using Frustrated Lewis Pairs *$Chase P.A., Hastie J.J.M., Thomson J.W., Pasternak A.S., Stephan D.W.
14:20 01914 Evolution of High Performance Organic Solar Cells at UCSB: From Lewis Acid-Base Adducts to Solution Processed Small Molecule Solar Cells with Record Power Conversion Efficiencies Welch G.C., Heeger A., $Bazan G.
14:40 01915 Enhancing Heavy Oil Recovery Using a New Dual Polymer System Jaska C., Cobos S., Fletcher P.
15:00 01916 Disease Modifying Small Molecules for the Treatment of Alzheimer's Disease *Wood T.K., $Reed M.
15:20 01917 Ambient Temperature Synthesis and Theoretical Analysis of Soluble Poly(oxothiazenes) *$McWilliams A.R., Aldeva V., Gossage R.A., Shuoprasad M.
15:40 Coffee Break
16:00 01918 Silver(I)-oligothiophene Coordination Polymers with Linkers of Various Lengths - Structural Similarities and Differences *$MacKinnon C.D., Andreychuk N.R., Boissy C.A., D'Aleo D.N., Assoud A.
16:20 01919 Copper(I) Amide Precursors for Copper Film Formation Blackwell J.M., Morrison D.M., Clendenning S.
16:40 01920 b-Agostic Isomery in Amidoborane Complexes Forster T.D., MacLean M., Roesler R., Tuononen H.M.
17:00 01921 Direct Arylation/Heteroarylation Polycondensation Reactions *Mercier L.G., Leclerc M.
17:20 End of Session

INGlen 201

Solid State Chemistry (joint with MT4)

13:40 See MT4.

17:20 End of Session


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